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ENVIS Technical Report 108, March 2017 |
FOAMING OR ALGAL BLOOM IN WATER BODIES OF INDIA: REMEDIAL MEASURES - RESTRICT PHOSPHATE (P) BASED DETERGENTS
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T.V. Ramachandra Durga Madhab Mahapatra Asulabha K S
Sincy Varghese |
Energy & Wetlands Research Group, Centre for Ecological Sciences,
Indian Institute of Science, Bangalore, Karnataka, 560 012, India.
E Mail: cestvr@ces.iisc.ernet.in,
Tel: 91-080-22933099, 2293 3503 extn 101, 107, 113
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Annexure
PHOSPHORUS: CHEMISTRY and USES
P |
Melting point |
44.1° C |
Boiling point |
280° C |
Density |
1.8 g/cm³ |
Appearance |
Phosphorus occurs in more than one form. One of these is waxy and white, and another is a dark, red powder. |
Other physical properties |
The waxy, white form of phosphorus glows in the dark. |
Chemical properties |
Phosphorus is insoluable in water. The waxy, white form is very reactive and can explode in air. (It burns at 35 °C.) It is also very poisonous. The powdery form is less reactive, although it burns in air. It is not very toxic. |
Compounds |
Calcium phosphate, a natural rock used to make phosphate fertilizers, is one compound of phosphorus. |
Uses |
Phosphorus is alloyed with bronze. It is also used in incendiary bombs and match heads. |
Notes |
Phosphorus compounds play an important role in the use of energy in living things. |
SOURCE |
Properties of Matter
http://www.propertiesofmatter.si.edu/Phosphorus.html |
White Phosphorous |
White phosphorus is a soft, waxy, flammable substance, consisting of tetrahedral P4 molecules; it is often slightly yellowish because of the presence of impurities (hence, it is sometimes imaginatively known as yellow phosphorus). White phosphorus is highly reactive, and spontaneously ignites at about 30°C in moist air. It is usually stored under water, to prevent exposure to the air. It is also extremely toxic, even in very small quantities. |
Hazards: White phosphorus is toxic (the approximate fatal dose is about 50 to 100 mg. Even in very small quantities, it produces severe gastrointestinal irritation, diarrhea, and liver damage. It also causes burns when it comes in contact with skin. Chronic exposure to white phosphorus causes bony necrosis (especially of the jaw, a condition called "phossy-jaw") and anemia.
https://www.angelo.edu/faculty/kboudrea/demos/burning_phosphorus/burning_phosphorus.htm
http://chandrasekaran.tripod.com/uses.htm |
Use values of Phosphorous |
HEALTH: |
In living beings, phosphorus is found in bones, teeth, nucleic acids (DNA and RNA), in the energy carriers (such as ATP), lipids, proteins and enzymes. This highlights that phosphorus is vital for biological organisms. |
Initiates Fire |
Phosphorus catches fire readily, it is used in match sticks; red phosphorus is used in "safety matches" and is less volatile and less poisonous. |
Flame retardants |
Phosphorus in its elemental form is used to make fire, while in the form of derived chemicals it is used to stop or reduce the hazards of fire. |
Uses |
- Surfactants, Cleaners:
- Phosphorus compounds (small molecules or polymer) are very useful in the synthetic polymers, paints and protective coatings for wood, the plasticizer/flame-retardant (and fire-resistance).
- Organo phosphates with good lubrication, thermal stablility and fire-resistant properties are used as high temperature lubricants.
- Metal Treating, Electroplating of copper or zinc, their pyrophosphate is used as electrolyte (along with potassium pyrophosphate).
- Water Treatment - to convert hard water to soft water by removing the metal ions as insoluble metal phosphates.
- tooth pastes (cavity protection or tartar control), in shampoos and many more commonly used items.
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Dr. T.V. Ramachandra
Centre for Sustainable Technologies, Centre for infrastructure, Sustainable Transportation and Urban Planning (CiSTUP), Energy & Wetlands Research Group, Centre for Ecological Sciences, Indian Institute of Science, Bangalore – 560 012, INDIA.
E-mail : cestvr@ces.iisc.ernet.in
Tel: 91-080-22933099/23600985,
Fax: 91-080-23601428/23600085
Web: http://ces.iisc.ernet.in/energy
Durga Madhab Mahapatra Energy & Wetlands Research Group, Centre for Ecological Sciences, Indian Institute of Science, Bangalore – 560 012, INDIA.
E-mail: durgamadhab@ces.iisc.ernet.in
Asulabha K SEnergy & Wetlands Research Group, Centre for Ecological Sciences, Indian Institute of Science, Bangalore – 560 012, INDIA.
E-mail: asulabha@ces.iisc.ernet.in
Sincy VargheseEnergy & Wetlands Research Group, Centre for Ecological Sciences, Indian Institute of Science, Bangalore – 560 012, INDIA.
E-mail: sincy@ces.iisc.ernet.in
Citation:Ramachandra T V, Durga Madhab Mahapatra, Asulabha K S, Sincy Varghese, 2017. Foaming or Algal Bloom in Water bodies of India: Remedial Measures - Restrict Phosphate (P) based Detergents, ENVIS Technical Report 108, Environmental Information System, CES, Indian Institute of Science, Bangalore 560012.
Contact Address : |
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Dr. T.V. Ramachandra
Energy & Wetlands Research Group,
Centre for Ecological Sciences, TE 15, New Biology Building, Third Floor, E Wing, [Near D Gate], Indian Institute of Science, Bangalore – 560 012, INDIA.
Tel : 91-80-22933099 / 22933503-extn 107
Fax : 91-80-23601428 / 23600085 / 23600683 [CES-TVR]
E-mail : cestvr@ces.iisc.ernet.in, energy@ces.iisc.ernet.in,
Web : http://wgbis.ces.iisc.ernet.in/energy |
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