Subject: Amorphous Silicon Based Solar Cells- Solar Energy


AMORPHOUS SILICON-BASED SOLAR CELLS COME INTO THEIR OWN

Contact: A'ndrea Elyse Messer
Phone: 814-865-9481
aem1@psu.edu
Penn State

San Francisco -- Three companies will mass-produce amorphous
silicon-based solar cells this year, which may spell the beginning
of commercially cost effective solar power, according to a Penn
State researcher.

"The next four or five years could determine the future of the
amorphous silicon photovoltaic industry," says Dr. Christopher R.
Wronski, the Leonhard Professor of Microelectronic Materials and
Devices.

The 1970s energy crisis stirred interest in commercial solar power,
and the discovery that amorphous silicon, laid down as a thin film
using standard depositional techniques, could be used for solar
cells, gave hope to the field.

"Unfortunately for the solar industry, 20 years ago we discovered
the Staebler-Wronski Effect," Wronski told attendees at the
Materials Research Society conference today (Apr. 3) in San
Francisco. "Ironically, the sunlight that produces electricity in
these amorphous solar cells, also degrades their efficiency."

The original amorphous silicon solar cells had efficiencies of 1
to 2 percent, but in a short time, initial efficiencies reached 10
percent. By the mid-1980s, large area panels measuring a square
foot could be made and by the mid-1990s, these large panels had
stabilized efficiencies of 10 percent.

"But for initial efficiencies, degradation by exposure to sunlight
causes 20 to 30 percent efficiency loss, lowering the available
power over time," says Wronski.

"We still don't agree on the mechanism behind the degradation, but
materials and manufacturing improvements have compensated to the
point where companies now feel they can economically mass produce
amorphous silicon solar cells," says Wronski.

The three companies that plan to market a combined annual output
of 25 megawatts of capacity are Solarex Corporation, United solar
Systems Corporation (U.S.S.C.) and Canon Japan. Solarex is aiming
their marketing at solar farms and plans to produce 10 megawatts
of capacity per year. U.S.S.C. and Canon are focusing on the
rooftop market with annual output of 20 and 5 megawatts of capacity
respectively. This rooftop market consists of urban rooftops with
solar cells covering large areas.

Amorphous silicon-based solar cells are deposited on thin sheets
of base material, usually glass but sometimes plastic or a metal.These cells
consist of a conducting layer and three very thin films
of amorphous silicon-based material with the middle layer
electrically neutral and the bottom and top layers having opposite
electrical properties. Large area solar panels are made of smaller
solar cells connected in series.

While eliminating the Staebler-Wronski Effect is not currently
possible, engineering approaches have been able to mitigate the
effect on power production. Making the silicon layers thinner
decreases the degree of degradation which is caused by
sunlight-induced defects in the material. Changes in the
composition of the silicon material have also helped with
efficiency.

Unlike other light-induced chemical changes like those produced
when light hits photographic film, the Staebler-Wronski Effect is
reversible by annealing. By heating the material to 300 degrees
Fahrenheit, the degradation is reversed, but, while this is a
worthwhile laboratory approach, it does not help commercially,
because the materials will simply degrade again when exposed to
sunlight.

The most inventive approach to increasing conversion of sunlight
to power has been to stack solar cells on panels. This increases
both the stability and the efficiency. Recently, the stacking of
three cells has achieved an increase in initial efficiency to over
14 percent.

Today, the 700 milliwatts of power from the sun that fall on a
square inch of solar cell is converted by a double junction solar
cell, at 8 percent efficiency, to produce 56 milliwatts per square
inch and by a triple junction solar cell to produce 100 milliwatts
per square inch.

"That isn't a lot of power," says Wronski, "but it is free energy
and all that is needed is a large area."

EDITORS: Dr. Wronski can be reached at (814) 865-0930.

For other Penn State news, please visit our Home Page on the Web
at:   http://www.psu.edu/ur/
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