Subject: Alkali in grasses

Roger Samson (REAP-Canada) presented the results of work in Canada to reduce
ash and alkali in grasses, particularly switchgrass, for use as fiber and
fuel.
His findings help to explain why, in 1992, we found decreasing chlorine and
alkali in wheat straw as we moved north from the Mexican border and across
different soil types.

Reducing these elements should reduce deposition and make deposits easier to
remove from heat transfer surfaces. It remains to be seen whether fuel and
fiber uses can support the (20-25%) lower yield and spring harvest
necessary to
obtain lower ash and alkali. Benefits are likely to be site specific.


Tom Miles   

Roger's Abstract from: BioEnergy ’98: Expanding BioEnergy Partnerships,
Madison, WI
Great Lakes Regional Biomass Energy Program
<http://www.cglg.org/projects/biomass>http://www.cglg.org/projects/biomass
COPYRIGHT 1998

STRATEGIES TO REDUCE THE ASH CONTENT IN PERENNIAL GRASSES
Roger Samson and Bano Mehdi
Resource Efficient Agricultural Production-Canada
Box 125, Ste. Anne de Bellevue, Quebec, H9X 3V9, Canada
REAP@interlink.net

ABSTRACT
Perennial grasses have been identified as the lowest cost dedicated
agricultural feedstock
for energy and agri-fibre markets. However, it is of paramount importance that
the ash
content of these feedstocks be reduced so as to facilitate their
commercialization. High
ash contents are particularly troublesome for achieving efficient combustion
when used
for bioenergy applications, and in chemical recovery systems, in the pulp and
paper
industry.

The major component of ash is silica. Warm season (C4) grasses are found to
have
lower
silica levels than C3 grasses owing primarily to the fact that they utilize
water 50% more
efficiently. Silica levels in grasses are also highly influenced by the
monosilicic acid
content of soils. As a result, clay soils produce higher silica containing
feedstocks than
sandy soils. Silica levels are lowest in the stem fraction of grasses, and
highest in
inflorescences, leaves, and leaf sheaths. Selection for higher stem content
will help to
reduce the plant’s ash content, while increasing the desirable feedstock
characteristics,
such as cellulose content, which is important for ethanol and pulp and paper
markets.
Reducing the potassium and chlorine contents of feedstocks grown for fuel
purposes is
important to improve combustion efficiencies. The chlorine content of
feedstocks is
strongly influenced by fertilization practices and can be minimized by using
chlorine free
fertilizers. Potassium and chlorine contents can be reduced to similar levels
as wood
chips by overwintering the grasses, however, there is a trade off in that
lower
yields are
harvested. The feedstock production cost of overwintered switchgrass is lower
than short
rotation forestry, and switchgrass provides similar properties for combustion
as wood.

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Thomas R. Miles		tmiles@teleport.com			        
Technical Consultants, Inc.	Tel (503) 292-0107/646-1198
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